absolute reaction rate sentence in Hindi
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- Yakov Frenkel represented diffusion process in condensed matter as an absolute reaction rates to this quasichemical representation of diffusion.
- TST is also referred to as " activated-complex theory, " " absolute-rate theory, " and " theory of absolute reaction rates ."
- In his PhD thesis, which he defended in 1914, he developed a general theory on absolute reaction rates, in which he used concepts of both thermodynamic and kinetic origin, describing the activation dependent phenomena as the movement of representative points in space.
- TST has been less successful in its original goal of calculating absolute reaction rate constants because the calculation of absolute reaction rates requires precise knowledge of potential energy surfaces, but it has been successful in calculating the standard enthalpy of activation ( ? ! " H " u ), the standard entropy of activation ( ? ! " S " u ), and the standard Gibbs energy of activation ( ? ! " G " u ) for a particular reaction if its rate constant has been experimentally determined . ( The ! notation refers to the value of interest " at the transition state " .)
- TST has been less successful in its original goal of calculating absolute reaction rate constants because the calculation of absolute reaction rates requires precise knowledge of potential energy surfaces, but it has been successful in calculating the standard enthalpy of activation ( ? ! " H " u ), the standard entropy of activation ( ? ! " S " u ), and the standard Gibbs energy of activation ( ? ! " G " u ) for a particular reaction if its rate constant has been experimentally determined . ( The ! notation refers to the value of interest " at the transition state " .)
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