The same ion has a ( HO ) Zn ( OH ) bending vibration at 300 cm " 1.
2.
For ammonia, NH 3, the symmetric bending vibration is observed as two branches near 930 cm " 1 and 965 cm " 1.
3.
The band around 6.3 ?m ( 1590 cm " 1 ) is due to the HOH bending vibration; the considerable breadth of this band is due to the presence of extensive rotational fine structure.
4.
The IR spectrum of plain methane has two C-H bands from symmetric and asymmetric stretching at around 3000 cm " 1 and two bands around 1400 cm " 1 from symmetrical and asymmetric bending vibrations.
5.
In the spectrum of CH 5 + three asymmetric stretching vibrations are present around 2800 3000 cm " 1, a rocking vibration at 1300 cm " 1, and a bending vibration at 1100 1300 cm " 1.
6.
This so-called inversion doubling arises because the symmetric bending vibration is actually a large-amplitude motion known as inversion, in which the nitrogen atom passes through the plane of the three hydrogen atoms, similar to the inversion of an umbrella.
7.
For S N 2 reactions, bending vibrations still play an important role for the kinetic isotope effect, but stretching vibrational contributions are of more comparable magnitude, and the resulting kinetic isotope effect may be normal or inverse depending on the specific contributions of the respective vibrations.
8.
:: The bending vibrations of the bar will be at a much lower frequency, http : / / hyperphysics . phy-astr . gsu . edu / hbase / music / barres . html may be helpful ( I haven't checked it thoroughly ).
9.
N . O . Myklestad, " A New Method of Calculating Natural Modes of Uncoupled Bending Vibration of Airplane Wings and Other Types of Beams ", " Journal of the Aeronautical Sciences " ( Institute of the Aeronautical Sciences ), Vol . 11, No . 2 ( 1944 ), pp . 153 162.
10.
If the zero-point energy difference between the stretching vibrations of a carbon-hydrogen and carbon-deuterium bond is allowed to disappear in the transition state, the expression given above predicts a maximum for k H / k D as 6.9 . If the weakening of two bending vibrations are also taken into account, k H / k D values as large as 15-20 can be predicted.
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