Most thermometers are originally calibrated to a constant-volume gas thermometer.
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Such systems are known as " ideal gas thermometers ".
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For such measurements a gas thermometer is more suitable.
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The ideal gas thermometer is, however, not theoretically perfect for thermodynamics.
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These include helium vapor pressure thermometers, helium gas thermometers, monochromatic radiation thermometers.
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So a gas thermometer, no matter how small or unobtrusive, is incapable of measuring negative temperatures.
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Although it is not a particularly convenient device, the gas thermometer provides an essential theoretical basis by which all thermometers can be calibrated.
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In 1848, he extended the Carnot Clapeyron theory still further through his dissatisfaction that the gas thermometer provided only an operational definition of temperature.
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Other thermometers ( e . g . mercury thermometers, which display the volume of mercury to the observer ) may now be constructed, and calibrated against the ideal gas thermometer.
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As a practical matter it is not possible to use a gas thermometer to measure absolute zero temperature since the gases tend to condense into a liquid long before the temperature reaches zero.
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