In electric multipole radiation, the electric field has a radial component; in magnetic multipole radiation, the magnetic field has a radial component.
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Higher electric and magnetic multipole moments cannot be predicted by this simple version of the shell model, for the reasons similar to those in the case of deuterium.
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Both ordinary and collision-induced spectra may be observed in emission and absorption and require an electric or magnetic multipole moment-in most cases an electric dipole moment-to exist for an optical transition to take place from an initial to a final quantum state of a molecule or a molecular complex . ( For brevity of expression we will use here the term " molecule " interchangeably for atoms as well as molecules ).
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