The general disaccharide unit consists of an N-acetyl-hexosamine and a hexose or hexuronic acid, either or both of which may be sulfated.
12.
He received his PhD from Fitzwilliam College, Cambridge in 1927 for work on isolating an organic acid, which he then called " hexuronic acid ", from adrenal gland tissue.
13.
Szent-Gy�rgyi suspected hexuronic acid, which he had isolated from adrenal glands, to be the antiscorbutic agent, but he could not prove it without an animal-deficiency model.
14.
In late 1931, King's lab obtained adrenal hexuronic acid indirectly from Szent-Gy�rgyi and, using their animal model, proved that it is vitamin C, by early 1932.
15.
They had also considered hexuronic acid as being the vitamin, but had been put off the trail when a coworker made the explicit ( and mistaken ) experimental claim that this substance was not the antiscorbutic substance.
16.
Moreover, glucuronolactone is hydrolyzed in the body ( like butyrolactone ) to glucuronic acid, which may be oxidized to glucaric acid, or isomerized to another hexuronic acid, so there is no reasonable toxicity mechanism.
17.
Finally, in late 1931, Szent-Gy�rgyi gave Svirbely, formerly of King's lab, the last of his adrenal-derived hexuronic acid with the suggestion that it might be the anti-scorbutic factor.
18.
HS-O-sulfotransferase ( Hs2st ) occupies a critical position in the succession of enzymes responsible for the biosynthesis of HS, catalysing the transfer of sulfate to the C2-position of selected hexuronic acid residues within the nascent HS chain.
19.
After being fed a meal of paprika peppers, a common spice and food in the Hungarian diet, Szent-Gy�rgyi was inspired to assay it for hexuronic acid, and found it present in large amounts without the contaminating sugars from sweeter plants.
20.
L "'- hexuronic acid, althogh he did not know the stereochemistry at that time ) from animal adrenal glands at the Mayo clinic, and suspected it to be the antiscorbutic factor, but could not prove this without a biological assay.
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