Which of the possible hydrogen transfers is rate determining can be shown by measuring the kinetic effects of substituting each hydrogen by deuterium, its stable isotope.
12.
It is worth noting that a suitable hydrogen acceptor / donor for a given reaction must be chosen to provide sufficient thermodynamic incentive for the desired hydrogen transfer.
13.
Since carbonization is a pyrolytic reaction, it is considered a complex process in which many reactions take place concurrently such as dehydrogenation, condensation, hydrogen transfer and isomerization.
14.
Based on the process of endosymbiotic theory ( SET ), the hydrogen hypothesis ( mostly a process of symbiosis where hydrogen transfer takes place among different species ), and the syntrophy hypothesis.
15.
These findings indicate that the prevailing geometries are in these two cases unfavourable for the rearrangement to occur and the C? H N bond angle required for the intramolecular hydrogen transfer cannot be easily attained.
16.
The zwitterionic nature of the molecule makes this highly water-soluble, as the presence of keto / enol tautomeric relationship, where a hydrogen transfer results in two distinct structures ( Figure 2 ).
17.
One of the most highly cited papers involving the genus " Ruminococcus " is a paper describing interspecies hydrogen transfer between " Ruminococcus albus " and " Wolinella succinogenes ".
18.
In humans a mechanism has been suggested which involves a hydrogen transfer between C1 and C2, mediated by Tyr278, and the movement of a proton from O1 and O2 mediated by the associated Zn2 + ion.
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