Basically, gas is expanded through a valve which causes energy to be absorbed against the intermolecular forces of the gas, which results in a net temperature decrease as long as the initial temperature of the gas is below the inversion temperature.
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On the other hand, nitrogen and oxygen, the two most abundant gases in air, have inversion temperatures of 621 K ( 348 �C ) and 764 K ( 491 �C ) respectively : these gases can be cooled from room temperature by the Joule Thomson effect.
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Empirically, it is found that almost all gases cool during a Joule expansion at all temperatures investigated; the exceptions are helium, at temperatures above about 40 K, and hydrogen, at temperatures above about 200 K . This temperature is known as the inversion temperature of the gas.
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