Here, with a group of his doctoral students, he proved the structure and existence of the compounds of muscone and civet, the scents derived from the musk deer and the civet cat.
12.
However this claim has been challenged by another report that the human musk-recognizing receptor, OR5AN1 that robustly responds to cyclopentadecanone and muscone, fails to distinguish isotopomers of these compounds in vitro.
13.
Specifically, Block et al . report that the human musk-recognizing receptor, OR5AN1, identified using a heterologous olfactory receptor expression system and robustly responding to cyclopentadecanone and muscone, fails to distinguish isotopomers of these compounds in vitro.
14.
Macrocyclic lactones ( cyclopentadecanolide, 15-pentadec-11 / 12-enolide ) have odors similar to macrocyclic ketones of animal origin ( muscone, civetone ), but they can be prepared more easily, for example, by depolymerization of the corresponding linear polyesters.
15.
In response to the 2013 paper on cyclopentadecanone, Block et al . report that the human musk-recognizing receptor, OR5AN1, identified using a heterologous olfactory receptor expression system and robustly responding to cyclopentadecanone and muscone ( which has 30 hydrogens ), fails to distinguish isotopomers of these compounds in vitro.
16.
For example, the key cyclization step in the total synthesis of ( R )-(-)-Muscone was an intramolecular asymmetric addition of a vinylzinc derivative to an aldehyde using a chiral amino-isoborneol ligand ( Figure " ( a ) Asymmetric addition of alkenylzinc to aldehyde in the total synthesis of muscone " ).
17.
For example, the key cyclization step in the total synthesis of ( R )-(-)-Muscone was an intramolecular asymmetric addition of a vinylzinc derivative to an aldehyde using a chiral amino-isoborneol ligand ( Figure " ( a ) Asymmetric addition of alkenylzinc to aldehyde in the total synthesis of muscone " ).
18.
In response to Turin's 2013 paper, involving deuterated and undeuterated isotopomers of the musk cyclopentadecanone, report that the human musk-recognizing receptor, OR5AN1, identified using a heterologous olfactory receptor expression system and robustly responding to cyclopentadecanone and muscone ( which has 30 hydrogens ), fails to distinguish isotopomers of these compounds in vitro.
19.
Global replacement of all hydrogens in muscone was achieved by heating muscone with Rh / C in D 2 O at 150 �C . It was found that the human musk-recognizing receptor, OR5AN1, identified using a heterologous olfactory receptor expression system and robustly responding to muscone, fails to distinguish the so-prepared isotopomers of muscone in vitro.
20.
Global replacement of all hydrogens in muscone was achieved by heating muscone with Rh / C in D 2 O at 150 �C . It was found that the human musk-recognizing receptor, OR5AN1, identified using a heterologous olfactory receptor expression system and robustly responding to muscone, fails to distinguish the so-prepared isotopomers of muscone in vitro.
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