He worked in the group of Glenn Seaborg, on the development of the PUREX process for separation of plutonium and uranium and was involved in the extraction of the first gram of plutonium produced in Chicago Pile-1.
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In brief, the PUREX process is a liquid-liquid extraction ion-exchange method used to reprocess spent nuclear fuel, in order to extract primarily uranium and plutonium, independent of each other, from the other constituents.
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A very important case is the PUREX process ( plutonium-uranium extraction process ) which is used to separate the plutonium and the uranium from the spent fuel products from a nuclear reactor, and to be able to dispose of the waste products.
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A very important case is the PUREX process ( plutonium-uranium extraction process ), which is used to separate the plutonium and the uranium from the spent fuel products from a nuclear reactor, and to be able to dispose of the waste products.
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In July 1958, Nehru authorized " Project Phoenix " to build a reprocessing plant with a capacity of 20 tons of fuel a year a size to match the production capacity of CIRUS . The plant used the PUREX process and was designed by the American firm Vitro International.
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Currently extraction into kerosene is preferred, using a ligand such as tri-" n "-butyl phohsphate, TBP . In the PUREX process, which is commonly used in nuclear reprocessing, uranium ( VI ) is extracted from strong nitric acid as the electrically neutral complex [ UO 2 ( TBP ) 2 ( NO 3 ) 2 ].
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The PUREX process can be modified to make a UREX ( " UR " anium " EX " traction ) process which could be used to save space inside high level nuclear waste disposal sites, such as Yucca Mountain nuclear waste repository, by removing the uranium which makes up the vast majority of the mass and volume of used fuel and recycling it as reprocessed uranium.
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Adding a second extraction agent, octyl ( phenyl )-N, N-dibutyl carbamoylmethyl phosphine oxide ( CMPO ) in combination with tributylphosphate, ( TBP ), the PUREX process can be turned into the TRUEX ( " TR " ans " U " ranic " EX " traction ) process this is a process which was invented in the USA by Argonne National Laboratory, and is designed to remove the transuranic metals ( Am / Cm ) from waste.
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