To obtain the absolute value, we need the Third Law of Thermodynamics, which states that S = 0 at absolute zero for perfect crystals.
12.
The third law of thermodynamics is consistent with this definition, since zero entropy means that the macrostate of the system reduces to a single microstate.
13.
Note that the above equation is flawed as the temperature approaches zero, the entropy approaches negative infinity, in contradiction to the third law of thermodynamics.
14.
:You could say that, yes . ( This is one reason why, as the third law of thermodynamics says, zero tempareture is unobtainable ).
15.
The entropy of a pure crystalline structure can be 0 J mol " 1 K " 1 only at 0K, according to the third law of thermodynamics.
16.
The heat capacity must be zero at zero temperature in order for the above integral not to yield an infinite absolute entropy, which would violate the third law of thermodynamics.
17.
To obtain the absolute value of the entropy, we need the third law of thermodynamics, which states that " S " = 0 at absolute zero for perfect crystals.
18.
According to the third law of thermodynamics, a system at absolute zero temperature exists in its ground state; thus, its entropy is determined by the degeneracy of the ground state.
19.
Stating that \ displaystyle \ kappa cannot go to zero is analogous to the third law of thermodynamics which states, the entropy of a system at absolute zero is a well-defined constant.
20.
This is because the entropy of an ideal gas at its absolute zero of temperature is not a positive semi-definite quantity, which puts the gas in violation of the third law of thermodynamics.
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