By lowering the energy of the transition state, it allows a greater population of the starting material to attain the energy needed to overcome the transition energy and proceed to product.
12.
In this approach, an ensemble of nuclear geometries is built in the initial state and the transition energies and transition moments to the other states are computed for each geometry in the ensemble.
13.
The strength of interaction with the counterion affects the energy of this antibonding orbital; thus, in colorless chloryl compounds, strong interactions with the counterion, corresponding with the higher covalent character of the bonding, shift the transition energy out of the visible spectrum.
14.
Like a bigger brother holding his flailing sibling at bay by simply palming his forehead, the Spurs stymied several Knicks'runs led by Latrell Sprewell's transition energy by simply pounding the ball into their Twin Towers and getting five clutch 3-pointers by Jaren Jackson.
15.
However, at the temperature of liquid hydrogen, not enough heat energy is available to produce orthohydrogen ( that is, the transition energy between forms is large enough to " freeze out " at this low temperature ), and thus the parahydrogen form predominates.
16.
Since the Coulomb interaction couples \ Pi _ { \ omega, \ mathbf { k } } with all \ mathbf { k } values, the characteristic transition energy follows from the exciton energy, not the bare kinetic energy of an electron hole pair.
17.
Where F ( BC : x ) is the energy of interaction between the " B " and " C " level holes in a final atomic state " x " and the " R "'s represent intra-and extra-atomic transition energies accounting for electronic screening.
18.
Nonlinearities can result in both spatial and temporal harmonics in the near field at the nucleus, opening the range of possibilities for rapid transfer from the storage state to the upper lasing state using other kinds of triads involving transition energies at multiples of the optical laser quantum energy and at higher multipolarities.
19.
Reichardt's dye, a solvatochromic dye that changes color in response to polarity, gives a scale of " E T " ( 30 ) values . " E T " is the transition energy between the ground state and the lowest excited state in kcal / mol, and ( 30 ) identifies the dye.
20.
Examples of significant physical outcomes of this effect include the lowered melting temperature of mercury ( which results from 6s electrons not being available for metal bonding ) and the golden color of gold and caesium ( which results from narrowing of 6s to 5d transition energy to the point that visible light begins to be absorbed ).
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