11. That transition state will then be the rate-determining step of a given reaction. 12. Accordingly, the methyl transition state is very far to the right. 13. Rearrangements for which a chair transition state is geometrically impossible can nonetheless occur. 14. I'm also wondering if there any good candidate reactions for cyclic transition states . 15. This is different than the believed Zimmerman-Traxler model like transition state . 16. The suprafacial shift is strained transition state and is also unlikely. 17. The catalyst stabilizes the transition state more than it stabilizes the starting material. 18. The pericyclic transitions states involving concerted synchronous or concerted asynchronous processes. 19. Reaction coordinates can then be simulated, and transition state structures solved. 20. If transition state involves 4n electrons, the Mobius topology is aromatic and allowed.
