The activated complex of a reaction can refer to either the transition state or to other states along the reaction coordinate between reactants and products, especially those close to the transition state . u
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K Br + Br, in which the initial long-range attraction of the reactants leads to an activated complex resembling K + " " " Br " " " " Br.
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This can be visualized in terms of a reaction coordinate, where the transition state is the molecular configuration at the peak of the diagram while the activated complex can refer to any point near the maximum.
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However, whereas in Eyring theory the reaction partners become strongly coupled in the course of the reaction to form a structurally defined activated complex, in Marcus theory they are weakly coupled and retain their individuality.
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This started with the transition state theory ( also referred to as the activated complex theory ), which was first developed around 1935 by Polanyi, and introduced basic concepts in chemical kinetics that are still used today.
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It is the subject of transition state theory-also known as activated complex theory-which studies the standard Gibbs energy of formation ? ! "'G " " " ?" '.
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TCRs are molecules found on the surface of biologic medicines by combining engineered, cancer-recognizing TCRs with immune activating complexes, which, in theory, creates a drug that directs the immune system to kill cancer cells.
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The proposed mechanism suggests that in the first step, the spectator ligands undergo displacement reaction to produce an activated complex which is converted, via oxidative coupling of an alkyne and an azide to the ruthenium containing metallocyle ( Ruthenacycle ).
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Since the system is in complete equilibrium, the concentrations of [ AB l ] ! and [ AB r ] ! are equal, so that each concentration is equal to one-half of the total concentration of activated complexes:
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As illustrated in Figure 2, at any instant of time, there are a few activated complexes, and some were reactant molecules in the immediate past, which are designated [ AB l ] ! ( since they are moving from left to right ).
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