Light scattering in an ideal defect-free crystalline ( non-metallic ) solid which provides " no scattering centers " for incoming light will be due primarily to any effects of anharmonicity within the ordered lattice.
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In a system of oscillators with natural frequencies \ omega _ \ alpha, \ omega _ \ beta, . . . anharmonicity results in additional oscillations with frequencies \ omega _ \ alpha \ pm \ omega _ \ beta.
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*Note : Light scattering in an ideal defect-free crystalline ( non-metallic ) solid which provides " no scattering centers " for incoming lightwaves will be due primarily to any effects of anharmonicity within the ordered lattice.
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In practice, such plots often give curves because of unaccounted anharmonicity in the potential; furthermore, the low population of the higher states ( or the Franck Condon principle ) makes it difficult to experimentally obtain data at high values of v.
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Further examples of anharmonic oscillators include the large-angle pendulum; nonequilibrium semiconductors that possess a large hot carrier population, which exhibit nonlinear behaviors of various types related to the effective mass of the carriers; and ionospheric plasmas, which also exhibit nonlinear behavior based on the anharmonicity of the plasma.
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