When oils or fats are heated in a pan, multiple degradation reactions occur, including : autoxidation, thermal oxidation, polymerization, and cyclization.
22.
This involves autoxidation of fatty acid chains containing carbon-carbon double bonds and ultimately the formation of odoriferous, low molecular weight aldehydes, ketones and carboxylic acids.
23.
However, large doses of amphetamine may indirectly cause dopaminergic neurotoxicity as a result of hyperpyrexia, the excessive formation of reactive oxygen species, and increased autoxidation of dopamine.
24.
A more commercially-viable method is to allow autoxidation of an organic intermediate, 2-ethylanthrahydroquinone dissolved in an organic solvent, to oxidize to and 2-ethylanthraquinone.
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A branching in the fatty acid molecule or an autoxidation result in a large deviation from the straight-chain molecular structure, so that these compounds do not form urea adducts.
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Although virtually all types of organic materials can undergo air oxidation, certain types are particularly prone to autoxidation, including unsaturated compounds that have allylic or benzylic hydrogen atoms; these materials are converted to hydroperoxides by autoxidation.
27.
Although virtually all types of organic materials can undergo air oxidation, certain types are particularly prone to autoxidation, including unsaturated compounds that have allylic or benzylic hydrogen atoms; these materials are converted to hydroperoxides by autoxidation.
28.
This autoxidation complicates studies in that it is often difficult to determine if these epoxy fatty acids identified in linoleic acid-rich plant and mammalian tissues represent actual tissue contents or are artifacts formed during their isolation and detection.
29.
But whereas the curing of oils is the result of autoxidation at room temperature for a painting, for a pan, the thermoxidized oil undergoes a conversion into the hard surface of the seasoned pan at the high temperatures of cooking.
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