In a three-electrode cell, a counter electrode, also called an auxiliary electrode, is used only to make a connection to the electrolyte so that a current can be applied to the working electrode.
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Such isolation prevents any byproducts generated at the auxiliary electrode from contaminating the main test solution : for example, if a reduction is being performed at the working electrode in aqueous solution, oxygen may be evolved from the auxiliary electrode.
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Such isolation prevents any byproducts generated at the auxiliary electrode from contaminating the main test solution : for example, if a reduction is being performed at the working electrode in aqueous solution, oxygen may be evolved from the auxiliary electrode.
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The auxiliary electrode often has a surface area much larger than that of the working electrode to ensure that the half-reaction occurring at the auxiliary electrode can occur fast enough so as not to limit the process at the working electrode.
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The auxiliary electrode often has a surface area much larger than that of the working electrode to ensure that the half-reaction occurring at the auxiliary electrode can occur fast enough so as not to limit the process at the working electrode.
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