Then, a more accurate description is the canonical ensemble or grand canonical ensemble, both of which have complete correspondence to thermodynamics.
22.
Then, a more accurate description is the canonical ensemble or grand canonical ensemble, both of which have complete correspondence to thermodynamics.
23.
It should be noted that the ensemble average of the above Hamiltonian at g = 3N is equal to the canonical ensemble average.
24.
The principal thermodynamic variable of the canonical ensemble, determining the probability distribution of states, is the absolute temperature ( symbol : ).
25.
For large systems ( in the thermodynamic limit ) these other ensembles become essentially equivalent to the canonical ensemble, at least for average quantities.
26.
By endowing the configuration space with a probability measure built from a Hamiltonian in this way, the configuration space turns into a canonical ensemble.
27.
I see far more references, both inside and outside Wikipedia, to " Gibbs canonical ensemble " than to " Gibbs canonical assembly ".
28.
The path integral now resembles the partition function of statistical mechanics defined in a canonical ensemble with inverse temperature proportional to imaginary time, } }.
29.
As a result, the grand canonical ensemble can be highly inaccurate when applied to small systems of fixed particle number, such as atomic nuclei.
30.
For systems where the particle number is variable ( due to contact with a particle reservoir ), the correct description is the grand canonical ensemble.
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