Continuing down the pathway, the removal of the carbon skeleton of aspartate by SAICAR lyase results in 5-aminoimidazole-4-carboxamide ribonucleotide ( AICAR ).
22.
When the reactant is a silylmethanol the reaction is a 1, 2-brook rearrangement but rearrangements over larger carbon skeletons are also possible.
23.
When terpenes are modified chemically, such as by oxidation or rearrangement of the carbon skeleton, the resulting compounds are generally referred to as terpenoids.
24.
There are also purely structural classifications based on the presence of carbazole, ?-carboline or other units in the carbon skeleton of the alkaloid molecule.
25.
Related bicyclics are norbornadiene which has the same carbon skeleton but with two double bonds and norbornane which is completely saturated without double bonds.
26.
The sugars produced during carbon metabolism yield carbon skeletons that can be used for other metabolic reactions like the production of amino acids and lipids.
27.
When terpenes are modified chemically, such as by oxidation or rearrangement of the carbon skeleton, the resulting compounds are generally referred to as " terpenoids ".
28.
The effect has proved to be general, but if fluoro instead of perfluoroalkyl groups decorate the carbon skeleton, behavior can be very different, as the following example reveals.
29.
Transamination or deamination of amino acids facilitates entering of their carbon skeleton into the cycle directly ( as pyruvate or oxaloacetate ), or indirectly via the citric acid cycle.
30.
It is believed that this radical forms a carbon-cobalt bond to the coenzyme, which is then followed by the rearrangement of the substrate's carbon skeleton, thus producing a succinyl-CoA radical.
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