If the electron jumps, the transfer is much faster than the movement of the large solvent molecules, with the consequence that the nuclear positions of the reaction partners and the solvent molecules are the same before and after the electron jump ( Franck Condon principle ).
22.
If the electron jumps, the transfer is much faster than the movement of the large solvent molecules, with the consequence that the nuclear positions of the reaction partners and the solvent molecules are the same before and after the electron jump ( Franck Condon principle ).
23.
:It's rather nonintuitive, but light doesn't seem to accelerate or decelerate, it just always goes the same speed ( in a given medium ), similar to how electrons jump from one energy level to another, without seemingly ever having been in-between.
24.
"A posteriori " one may presume that in the systems where the reaction partners may diffuse freely the optimum distance for the electron jump may be sought, i . e . the distance for which & Delta; G ! = 0 and & Delta; G 0 =-& lambda; o.
25.
Other photons can be emitted, for instance when the electron jumps from n = 1 to n = 2, or from n = 1 to n = 3, etc . But the calculus always considers that the electron is in equilibrium between two forces, the electrical and the centripetal, when the atom emits a photon.
26.
I have learnt something in chemistry which goes lke this : the colour of a compound is the complementary of the wavelength of photon absorbed, when an electron jumps to a higher energy state . but in equilibrium, the no of electrons jumping up have to be equal to the no of electrons falling back, emitting the same wavelength photon ( corresponding to the energy difference ), so shouldnt the net result be white always ? Preceding contribs)
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