Immediately after the transition to the ground electronic state, the solvent molecules must also rearrange themselves to accommodate the new electronic configuration of the chromophore.
22.
For many molecules, the sharing of electrons allows each atom to attain the equivalent of a full outer shell, corresponding to a stable electronic configuration.
23.
A very large number of electronic configurations are needed to exactly describe any multi-electron system, and no energy can be associated with one single configuration.
24.
There are strict selection rules as to the electronic configurations that can be reached by excitation by light however there are no such rules for excitation by collision processes.
25.
Ammonia and ammonium have the same number of electrons in essentially the same electronic configuration, but ammonium has an extra proton that gives it a net positive charge.
26.
However, the electronic wave function is usually dominated by a very small number of configurations and therefore the notion of electronic configuration remains essential for multi-electron systems.
27.
There are rather strict selection rules as to the electronic configurations that can be reached by excitation by light however there are no such rules for excitation by collision processes.
28.
Thus, all three models for paramagnetic Hb-O 2 may contribute to some small degree ( by resonance ) to the actual electronic configuration of Hb-O 2.
29.
The splitting \ Delta E = B \ mu _ B \ Delta m _ l is " independent " of the unperturbed energies and electronic configurations of the levels being considered.
30.
When compounds in this oxidation state are formed, the outer shell " s " electrons are lost, yielding a bare zinc ion with the electronic configuration [ Ar ] 3d 10.
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