Thus a metastable state is one for which the free energy change between reactants and products is not minimal even though the composition does not change in time.
22.
In that same year he showed how the characteristics of the current produced could be used to calculate the free energy change in the chemical reaction producing the current.
23.
When an ion diffuses from a region of activity to another region of activity, there is a free energy change and this is what the pH meter actually measures.
24.
The enzymatic mechanism of forming oxaloacetate is very exothermic and thereby irreversible; the biological Gibbs free energy change ( ?% G? ) is-30kJmol " 1.
25.
The term'high energy'with respect to these bonds can be misleading because the negative free energy change is not due directly to the breaking of the bonds themselves.
26.
Thus a titration based on a change in temperature ( which permits observation of the enthalpy change ) will show a greater inflection than will curves obtained from sensors reacting to free energy changes alone.
27.
Three of the steps the ones with large negative free energy changes are not in equilibrium and are referred to as " irreversible "; such steps are often subject to regulation.
28.
They showed that the high free energy change of thioesters hydrolysis and corresponding to their low equilibrium constants, it is unlikely that these species could have accumulated abiotically to any significant extant in the Lost City fields.
29.
The intergrown phases may be planar or rodlike, depending on the volume proportions of the phases, their interfacial free energies, the rate of reaction, the Gibbs free energy change, and the degree of recrystallization.
30.
Note that the " standard " free energy change for the reaction is for the changes " from " the reactants in their standard states " to " the products in their standard states.
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