If a brand-new piece of glassware or a plastic container is used, crystals may not form because the container surface is too smooth to allow heterogeneous nucleation.
22.
This data is just one example but it does illustrate common features of the nucleation of crystals in that there is clear evidence for heterogeneous nucleation, and that nucleation is clearly stochastic.
23.
During the heterogeneous nucleation process in the nucleation chamber, particles grow up to 10 & 12 ?m large and so are conveniently detected by usual techniques, such as laser nefelometry ( measurement of light pulses scattered by the grown-up particles ).
24.
Is any law of thermodynamics being violated here ? ( Or does the oil conceivably become warmer and warmer, lowering likelihood of condensation with each new water being condensed ? ) AFAIK, oil is acting only like a heterogeneous nucleation-promoting catalyst-- it shouldn't change the equilibrium constant.
25.
However, it may be that indeed the homogeneous nucleation of ice at temperatures near-20 & # 8239; �C and above is " extremely " slow and so that whenever we see water freezing temperatures of-20 & # 8239; �C and above this is due to heterogeneous nucleation, i . e ., the ice nucleates in contact with a surface.
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