Furthermore, one is able to determine the ionic radii ( or more properly, the thermochemical radius ) using the Kapustinskii equation when the lattice energy is known.
22.
This is due to the greater size of the P 3 " and As 3 " ions, so that less lattice energy needs to be released for the salts to form.
23.
The polarisation can be calculated on the basis of higher-order Madelung constants and has to be included in the calculation of the lattice energy by using a generalised Born Haber cycle.
24.
Some older textbooks define lattice energy with the opposite sign, i . e . the energy required to convert the crystal into infinitely separated gaseous ions in vacuum, an endothermic process.
25.
See the article on lattice energy for a formal definition : basically, you calculate the coulomb interaction energy between each atom, and sum it all up to get the lattice energy.
26.
See the article on lattice energy for a formal definition : basically, you calculate the coulomb interaction energy between each atom, and sum it all up to get the lattice energy.
27.
The most widely discussed method first ranks the energies of all possible crystal structures using a customised DFT step to estimate the lattice energy and stability of each short-listed candidate structure.
28.
The latter happens because the hydration energy does not completely over come the lattice energy, and the remainder has to be taken from the water in order to compensate the energy loss.
29.
There is a linear relationship between cohesive energy density ( lattice energy per volume ) and Wooddell wear resistance, occurring between corundum ( H = 9 ) and diamond ( H = 42.5 ).
30.
Z " p " ] " ( where ) tend to dissociate into simple monohalide salts between M + and the most electronegative halogen, so that the monohalide has the highest lattice energy.
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