Furthermore, nitrosyl chloride is a powerful oxidizing agent, and oxidation of the alcohols with concomitant chlorination has been observed.
22.
In the absence of other radical sources or other proximal reactive groups, the alkyl radical recombines with the nitrosyl radical.
23.
Two series of nitrogen oxohalides are known : the nitrosyl halides ( XNO ) and the nitryl halides ( XNO 2 ).
24.
In addition the ruthenium in PUREX raffinate forms a large number of nitrosyl complexes which makes the chemistry of the ruthenium very complex.
25.
:Nitrosyl chloride can also be used to synthesise them from alcohols . talk ) 10 : 59, 28 May 2010 ( UTC)
26.
Nitrosyl chloride followed by base leads to the oxime 8 which can be reduced to " pinylamine " "'9 " '.
27.
Nitrosylated ferrous iron is particularly stable, as the binding of the nitrosyl ligand to ferrous iron ( Fe ( II ) ) is very strong.
28.
The alkyl radical formed after hydrogen atom transfer is susceptible to standard radical reactions when scavengers are present in sufficient excess to outcompete the nitrosyl radical.
29.
It is used as a method of replacing the nitrosyl from the modified cysteines and thus can serve in research of the redox modification of different proteins.
30.
However, recombination of the nitrosyl radical with the alkoxyl radical ( a reversal of the homolytic cleavage ) has been shown to proceed without scrambling of isotope labels.
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