Inorganic ozonides are formed by burning potassium, rubidium, or caesium in ozone, or by treating the alkali metal hydroxide with ozone; if potassium is left undisturbed in air for years it accumulates a covering of superoxide and ozonide.
22.
Because the superoxide releases the most energy when formed, the superoxide is preferentially formed for the larger alkali metals where the more complex anions are not polarised . ( The oxides and peroxides for these alkali metals do exist, but do not form upon direct reaction of the metal with oxygen at standard conditions . ) All the stable alkali metals except lithium can form red ozonides ( MO 3 ) through low-temperature reaction of the powdered anhydrous hydroxide with ozone : the ozonides may be then extracted using liquid ammonia.
23.
Because the superoxide releases the most energy when formed, the superoxide is preferentially formed for the larger alkali metals where the more complex anions are not polarised . ( The oxides and peroxides for these alkali metals do exist, but do not form upon direct reaction of the metal with oxygen at standard conditions . ) All the stable alkali metals except lithium can form red ozonides ( MO 3 ) through low-temperature reaction of the powdered anhydrous hydroxide with ozone : the ozonides may be then extracted using liquid ammonia.
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