Each p orbital on one atom overlaps one on the other atom, forming two pi bonds, giving a total of three bonds.
22.
Bonding usually discussed in the context of molecular orbital theory, which recognizes the triple bond as arising from overlap of s and p orbitals.
23.
For transition metal centres, the d and s orbitals are the primary valence orbitals, which are only weakly supplemented by the p orbitals.
24.
BUT we lose one p orbital to that pair of electrons stolen for aromaticity, so instead of sp3 we're downgraded to sp2!
25.
:I'm not sure that make sense, unless there is significant overlap between the bonding energies of the s and p orbitals.
26.
The stereoelectronic effects that affect the quilibrium is the interaction between the delocalized banana bonds and the empty p orbital on the boron atom.
27.
The question of whether the p orbitals actually participate in bonding has not been definitively resolved, but all studies indicate they play a minor role.
28.
However, the 2s can mix with the 2p orbitals in diberyllium, whereas there are no p orbitals in the valence level of hydrogen or helium.
29.
Rotation about the carbon carbon double bond is restricted because it incurs an energetic cost to break the alignment of the p orbitals on the two carbon atoms.
30.
As they had before a nearly closed filled p orbital ( 5 instead of 6 electrons ), the two paired electrons now sort of close off both orbitals.
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