The drawbacks of this reaction include the cross-reactivity of the nitrile oxide due to strong electrophilicity and slow reaction kinetics.
22.
Direct EDTA titrations with metal ions are possible when reaction kinetics are fast, for example zinc, copper, calcium and magnesium.
23.
My teaching experience suggests that discussing the forward and backward reaction kinetics can also help students to gain an intuitive understanding of activity.
24.
Successful applications for thermometric titrations are generally where titrant-titrand reaction kinetics are fast, and chemical equilibria are stoichiometric or nearly so.
25.
This together with uniformity of size and shape provides for very good accessibility and fast liquid-phase reaction kinetics, and rapid and efficient binding.
26.
My thesis work has led me to the problem of trying to define the reaction kinetics of a 10 um particle with small molecules in solution during vortexing.
27.
It is extensively used both in educational arena and industry to predicate the behavior of a process using material balance equations, equilibrium relationship, reaction kinetics, etc.
28.
Where reaction kinetics are slow, and direct titrations between titrant and titrand are not possible, indirect or back-titrations often can be devised to solve the problem.
29.
Similarly, a sharp increase ( or decrease ) in the reaction kinetics as a function of the average isotopic mass of a certain element is called here a resonance.
30.
It is common to model such a network with a set of coupled ordinary differential equations ( ODEs ) or stochastic ODEs, describing the reaction kinetics of the constituent parts.
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