Media of high ionic strength are used in stability constant determination in order to minimize changes, during a titration, in the activity quotient of solutes at lower concentrations.
22.
When the stability constants are quantitatively adjusted for these values they follow the trend that is predicted, in the absence of crystal field effects, between manganese and zinc.
23.
Warwick P, Evans N, Hall T, Vines S ( 2004 ) Stability constants of uranium ( IV )-?-isosaccharinic acid and gluconic acid complexes.
24.
Perfected by F . H . Spedding et al . in 1954, the method relies on the steady increase in stability constant of the lanthanide EDTA complexes with atomic number.
25.
If solubility in the organic phase is not an issue, a selectivity coefficient is equal to the ratio of the stability constants of the TBP complexes of two metal ions.
26.
Only [ H + ] T can be determined, therefore [ H + ] F must be estimated using the [ SO ] and the stability constant of HSO, K:
27.
Furthermore, stability constant values depend on the specific electrolyte used as the value of " ? " is different for different electrolytes, even at the same ionic strength.
28.
The diagram at the right shows the result of a refinement of the stability constants of Ni ( Gly ) +, Ni ( Gly ) 2 and ( where GlyH = glycine ).
29.
All published stability constant values refer to the specific ionic medium used in their determination and different values are obtained with different conditions, as illustrated for the complex CuL ( L = glycinate ).
30.
Both SIT and Pitzer parameters have been used in this context, For example, both sets of parameters were calculated for some uranium complexes and were found to account equally well for the ionic strength dependence of the stability constants.
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