A way to make a tetranitratoaluminate salt of a cation is to treat the chloride of the cation and aluminium chloride with liquid dinitrogen tetroxide pure or dissolved in nitromethane.
32.
Subsequent hydrogenation of "'13 "'followed by intramolecular cyclization with aluminium chloride forms the B ring and ( + )-totarylmethyl ether which is demethylated by boron tribromide to yield ( + )-totarol.
33.
He researched the chemistry of hydrocarbons and polymers, and developed the proton theory of aluminium chloride, which helped explain a variety of chemical reactions, publishing a book on the subject in 1941.
34.
The aluminium chloride adduct ( POCl 3 �AlCl 3 ) is quite stable, and so POCl 3 can be used to remove AlCl 3 completely from reaction mixtures at the end of a Friedel-Crafts reaction.
35.
Other methods to form methyldiboranes include reacting hydrogen with trimethylborane between 80 and 200 �C under pressure, or reacting a metal borohydride with trimethylborane in the presence of hydrogen chloride, aluminium chloride or boron trichloride.
36.
The major other uses of aluminium hydroxide is as a feedstock for the manufacture of other aluminium compounds : specialty calcined aluminas, aluminium sulfate, polyaluminium chloride, aluminium chloride, zeolites, sodium aluminate, activated alumina, aluminium nitrate.
37.
In studying the chemical reactions between alkenes and dienes, particularly in the presence of an aluminium chloride catalyst, he developed the proton theory of aluminium chloride, which helped explain a variety of chemical reactions, including cracking, polymerization and dehydrogenation.
38.
In studying the chemical reactions between alkenes and dienes, particularly in the presence of an aluminium chloride catalyst, he developed the proton theory of aluminium chloride, which helped explain a variety of chemical reactions, including cracking, polymerization and dehydrogenation.
39.
Aluminium chloride combined with aluminium in the presence of an arene can be used to synthesize bis ( arene ) metal complexes, e . g . bis ( benzene ) chromium, from certain metal halides via the so-called Fischer-Hafner synthesis.
40.
The yield is lower for 3-chloropyridine upon chlorination with molecular chlorine in the presence of aluminium chloride at 100 �C . Both 2-bromopyridine and 2-chloropyridine can be produced by direct reaction with halogen with a palladium ( II ) chloride catalyst.
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