Because the charge isn't dealt with as well in the case of acetic acid, its conjugate acid is more likely to snatch back protons from the solution than Cl -.
32.
The reverse of an acid-base reaction is also an acid-base reaction, between the conjugate acid of the base in the first reaction and the conjugate base of the acid.
33.
It works because, by adding either acid or base, the conjugate acid / base pair works by reacting with either an added acid OR an added base, and so neutralizes either.
34.
Under acidic conditions of pH 5 to 6, the pyrazinoic acid that slowly leaks out converts to the protonated conjugate acid, which is thought to diffuse easily back into the bacilli and accumulate.
35.
Trimethylsilylmethylamine ( Me 3 SiCH 2 NH 2 ) is a stronger base with a pKa of 10.96 for the conjugate acid than the carbon analogue neopentyl amine with pKa 10.21.
36.
I think the imidazole-type motif in Prilosec is responsible for the pKa ( pka of conjugate acid ) of 8.8-- but why the elevated pKa compared to normal imidazole?
37.
BH + is " log ( K ) for the dissociation of BH +, which is the conjugate acid of a very weak base B, with a very negative p " K"
38.
The ammonia is the conjugate acid of a weak base ( NH 3 ) and hence will react with water such that NH 4 + + H 2 O-> NH 3 + H 3 +.
39.
Note that it is conventional for basic compounds to quote a pK a which refers to the pK a of the conjugate acid rather than that of the basic compound itself, likewise for pK b when discussing acids.
40.
And it even says " " Historically, the equilibrium constant Kb for a base has been defined as the association constant for protonation of the base, B, to form the conjugate acid, HB +.
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