In this example, the complex has binding very similar to ferrocene, where one the Cp ligands is multiply substituted.
32.
In contrast to ferrocene, wherein the cyclopentadienyl rings are in a staggered conformation, those of ruthenocene crystallise with an eclipsed conformation.
33.
The uranium f orbitals interact substantially with the aromatic rings just as the d-orbitals in ferrocene interact with the Cp ligands.
34.
Ferrocenium salts are sometimes used as oxidizing agents, in part because the product ferrocene is fairly inert and readily separated from ionic products.
35.
A QRE with ferrocene or another internal standard, such as cobaltocene or decamethylferrocene, referenced back to ferrocene is ideal for nonaqueous work.
36.
A QRE with ferrocene or another internal standard, such as cobaltocene or decamethylferrocene, referenced back to ferrocene is ideal for nonaqueous work.
37.
This observation is not unexpected given that the cobalticinium cation and ferrocene are isoelectronic, although the bonding was not understood at the time.
38.
In terms of structure and bonding it resembles ferrocene, but with a methyl group on each of the carbons of the Cp rings.
39.
Consequently, the initial challenge was to definitively determine the structure of ferrocene in the hope that its bonding and properties would then be understood.
40.
The enzyme is reoxidized with an excess of a mediator reagent, such as a ferricyanide ion, a ferrocene derivative or osmium bipyridyl complex.
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