The LS state will have the smaller equilibrium distance-meaning that it has the larger bond force constant, ?LS > ?HS, and the transitions must fall within the thermal energy, k B T.
32.
Here it is assumed that application of the force " "'causes " "'the spring to expand and, having derived the force constant by least squares fitting, the extension can be predicted from Hooke's law.
33.
They should have taken control, even taken it early when they were driving the lane unchallenged, controlling the boards and forcing constant Missouri misses and turnovers, making the Tigers look like some disorganized street team.
34.
The period and frequency are determined by the size of the mass " m " and the force constant " k ", while the amplitude and phase are determined by the starting position and velocity.
35.
Conversely, when carbon's hybridization changes from sp 2 to sp 3, the out of plane bending force constants at the transition state increase and an inverse SKIE is observed with typical values of 0.8 to 0.9.
36.
Vulcanization of rubber creates disulfide bonds between chains, which limits the degrees of freedom and results in chains that tighten more quickly for a given strain, thereby increasing the elastic force constant and making the rubber harder and less extensible.
37.
There are two terms in the force law; what physical principle leads to those terms being present and other terms being absent, and what principle sets the value of the constant factors on each term ( the force constants G and ? )?
38.
The force constant of the bond can be found by Taylor expansion of V ( r ) around r = r _ e to the second derivative of the potential energy function, from which it can be shown that the parameter, a, is
39.
In general, smaller force constants in the transition state are expected to yield a normal kinetic isotope effect, and larger force constants in the transition state are expected to yield an inverse kinetic isotope effect when stretching vibrational contributions dominate the kinetic isotope effect.
40.
In general, smaller force constants in the transition state are expected to yield a normal kinetic isotope effect, and larger force constants in the transition state are expected to yield an inverse kinetic isotope effect when stretching vibrational contributions dominate the kinetic isotope effect.
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