However, for NOE, a negative value of " K ", the ratio of gyromagnetic ratios of the nuclei, may result in a " reduction " in signal intensity.
32.
For 15 N ( Nitrogen-15 NMR spectroscopy ) which has a negative gyromagnetic ratio, if the dipolar relaxation has to compete with other mechanisms, the observed 15 N signal can be near zero.
33.
The relaxation time, " T 1 " ( the average lifetime of nuclei in the higher energy state ) is dependent on the gyromagnetic ratio of the nucleus and the mobility of the lattice.
34.
Unlike NOE, no penalty is incurred by a negative gyromagnetic ratio in INEPT, it is therefore a useful method for enhancing the signal from nuclei with negative gyromagnetic ratio such as 15 N or 29 Si.
35.
Unlike NOE, no penalty is incurred by a negative gyromagnetic ratio in INEPT, it is therefore a useful method for enhancing the signal from nuclei with negative gyromagnetic ratio such as 15 N or 29 Si.
36.
These procedures rely on the fact that bulk magnetization due to nuclear spins precess in a magnetic field at a rate called the Larmor frequency, which is simply the product of the gyromagnetic ratio with the magnetic field strength.
37.
Equating the left and right hand sides, and noting that \ frac { 2 \ mu } { \ hbar } is the gyromagnetic ratio \ gamma, yields another form for the equations of motion of the Bloch vector
38.
Where g _ l = 1 and g _ s \ approx 2.0023192 ( the latter is called the anomalous gyromagnetic ratio; the deviation of the value from 2 is due to the effects of quantum electrodynamics ).
39.
Where is the actual strength of the magnet in units like gauss, and is the gyromagnetic ratio of the nucleus being tested which is in turn calculated from its magnetic moment and spin number with the nuclear magneton and the Planck constant:
40.
When applied a one-electron atom or ion, setting "'0 "'} } and to the appropriate electrostatic potential, additional relativistic terms include the spin-orbit interaction, electron gyromagnetic ratio, and Darwin term.
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