Hence, if ?H?1 is proportional to ?H?2 by a given factor, and if ?S?1 and ?S?2 follow a similar law ( same proportionality factor ), the inequality ( 17 ) is broken ( equality instead, so T H equals to the water thermolysis temperature ).
32.
Hence, a single reaction only offers one freedom degree ( T ) to produce hydrogen and oxygen only from heat ( though using Le Chatelier's principle would also allow to slightly decrease the thermolysis temperature, work must be provided in this case for extracting the gas products from the system)
33.
BjF can be obtained when either 2-( 1-chloroethenyl ) benzo [ c ] phenanthrene or 6-( 1-chloroethenyl ) chrysene is treated by flash vacuum thermolysis ( FVT ) at high temperatures ( > 900 �C ) followed by ring rearrangements ( ring contraction / expansion ) to selectively yield BjF . benzo [ k ] fluoranthene may also be converted via similar processes to BjF by FVT at temperatures e " 1100 �C ( 6 % yield ) or e " 1200 �C ( 11 % yield ) with 38 % mass recovery.
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