It is formed when triplet oxygen, the normal ground state, reacts with sensitizers, such as certain dyes and ketones, excited by radiation to their triplet states.
32.
The efficiency of Type-II processes is dependent upon the triplet state lifetime " ? " T and the triplet quantum yield ( ?T ) of the photosensitiser.
33.
If the dynamics of interest are much slower than the triplet state relaxation, the short time component of the autocorrelation can simply be truncated and the triplet term is unnecessary.
34.
As long as the molecule is in the long-lived dark state ( e . g . a triplet state ), it cannot be excited from the ground state.
35.
Molecular oxygen ( ) also exists in three lower-energy triplet states and one singlet state, as ground-state paramagnetic triplet oxygen and energized highly reactive diamagnetic singlet oxygen.
36.
Thus, in the helium atom, Hund's first rule correctly predicts that the 1s2s triplet state ( 3 S ) is lower than the 1s2s singlet ( 1 S ).
37.
This state has a slightly higher energy ( by about 9 kcal / mol ) than the triplet state, and its H-C-H angle is smaller, about 102?
38.
The excited electron can then undergo a second spin-forbidden inversion and depopulate the excited triplet state ( T1 ) by decaying to the ground state ( S0 ) via phosphorescence ( T1?
39.
The triplet state is not allowed in the ground state of the helium atom, since the spatial function in this case is symmetric and the spin function needs to be anti-symmetric.
40.
This excess excitation energy leads to an increase in the lifetime of singlet excited chlorophyll, increasing the chances of the formation of long-lived chlorophyll triplet states by inter-system crossing.
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