This means that the relative degree of unsaturation of alkenones can be used to estimate the temperature of the water in which the alkenone-producing organisms grew.
32.
An additional class of acyl-CoA dehydrogenase was discovered that catalyzes ?, ?-unsaturation reactions with steroid-CoA thioesters in certain types of bacteria.
33.
Desaturase enzymes ( such as those encoded by FADS1 ) regulate unsaturation of fatty acids through the introduction of double bonds between defined carbons of the fatty acyl chain.
34.
Treatment of that product with triethyl silane then reduces the ring unsaturation and cleaves the benzylic nitrogen bond on the auxiliary to yield as the optically pure trans isomer.
35.
The position of unsaturation is indicated by a numerical locant immediately preceding the "-yne " suffix, or'locants'in the case of multiple triple bonds.
36.
It is not surprising given this understanding of the forces involved that studies have shown that K a varies strongly with osmotic pressure but only weakly with tail length and unsaturation.
37.
I can totally see how increasing unsaturation ( via elimination or oxidising an alcohol into an aldehyde ) is oxidisation, because the organic compound actually sees electrons exit its system.
38.
Experiments suggest that the degree of unsaturation increases linearly with pressure for a breathing mixture of fixed composition, and decreases linearly with fraction of inert gas in the breathing mixture.
39.
The members of an alkylation series have the same degree of unsaturation and number of heteroatoms ( nitrogen, oxygen and sulfur ) but differ in the number of CH 2 units.
40.
The driving mechanism for gas elimination in this tissue is inherent unsaturation, also called partial pressure vacancy or the oxygen window, where oxygen metabolised is replaced by more soluble carbon dioxide.
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