Moreover, as global absolute chemistry was assigned on the basis of NOE correlations between the stereodefined L-mycarose sugar and the aglycone, the errors of the stereotetrad propagated to the other two stereocenters of the aglycone.
42.
"' Apigenin "'( 42, 5, 7-trihydroxyflavone ), found in many plants, is a natural product belonging to the flavone class that is the aglycone of several naturally occurring glycosides.
43.
He was subsequently an NIH postdoctoral fellow at Yale University with Professor Samuel J . Danishefsky, where he completed ( with M . Paz Cabal ), the first total synthesis of the aglycone of the antitumor agent calicheamicin.
44.
This revision led Hirama " et al " . to invert the other aglycone stereocenters as well, affording a revised structure of kedarcidin chromophore that differed only in the relative stereochemistry of the mycarose-bearing carbon, C10.
45.
The main bitter flavor of olives before curing results from oleuropein and its aglycone which total in content, respectively, 72 and 82 mg / 100 g in black olives, and 56 and 59 mg / 100 g in green olives.
46.
The lipophilic aglycone can be any one of a wide variety of organic structures originating from the serial addition of 10-carbon ( C10 ) terpene units to compose a C30 triterpene skeleton, often with subsequent alteration to produce a C27 steroidal skeleton.
47.
:i guess it shows you the aglycone of phloretin is active piece, not the glucose bit . phloretin is a protein kinase C inhibitor, as well as an inhibitor of a number of transporters, including the glucose transporters . so that's where the effect comes form, it's just coincidence phloridzin has glucose on it ..
48.
And then, the next pathway is catalyzed the formation of complex aglycone and anthocyanin composition by flavanone 3-hydroxylase ( F3H ), flavonoid 3'- hydroxylase ( F3'H ), dihydroflavonol 4-reductase ( DFR ), anthocyanidin synthase ( ANS ), UDP-glucoside : flavonoid glucosyltransferase ( UFGT ) and methyl transferase ( MT ).
49.
Glucose is transformed to NTP-L-ristoamine by StaA / B / E / J / I / K which is then added on to the staurosporine aglycone at 1 indole N by StaG . The StaN enzyme reorients the sugar by attaching it to the 2nd indole nitrogen into an unfavored conformation to form intermediated O-demethyl-N-demethyl-staurosporine.
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