The role of the pyridyl group in this catalytic cycle is evident when the ligand is replaced by triphenyl phosphine, and rates of catalysis a greatly decreased . 3 reference not specified-- > This catalytic process is an important step in the production of polymers, and other fine chemicals.
42.
Because hydromethanation is a catalytic process that does not rely on the combustion of carbonaceous solids to capture their energy value, it does not produce the nitrogen oxides ( NOx ), sulfur oxides ( SOx ) and particulate emissions typically associated with the burning of carbon feedstocks, including certain types of biomass.
43.
GLUD1 has two co-enzyme binding sites : one in the NAD-BD that is able to bind ether NAD + or NADP + and is directly involved in the catalytic process, and a second one, that has regulatory function, lying directly under the pivot helix, that can bind ADP, NAD +, or NADH, but does not bind NADPH well.
44.
However, it is possible to alter experimental conditions ( e . g ., temperature, pH ) " in vitro " such that some mammalian isoforms will alter the degree to which they produce mixtures of cyclic / acyclic products along with DAG . This catalytic process is tightly regulated by reversible phosphorylation of different phosphoinositides and their affinity for different regulatory proteins.
45.
These processes are of great industrial and environmental importance as they provide the bulk of sulfur used in industry ( Claus process and Contact process ), sulfur-free compounds that could otherwise not be used in a great number of catalytic processes, and also reduce the release of harmful sulfur compounds into the environment, particularly sulfur dioxide ( SO 2 ) which leads to acid rain.
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