These long chain compounds have surprising electronic properties-high electrical conductivity, for example-arising from sigma delocalization of the electrons in the chain.
42.
In the text of Tomlinson, however, we found that he uses " deterritorialization " to explain the phenomenon instead of using " delocalization ".
43.
This was shown in a single crystal X-ray diffraction study revealing shortened bond lengths in the heterocyclic portion of the ring suggesting electronic delocalization.
44.
The C 48 N 12 molecule was calculated to be an insulator, with the eight all-carbon rings forming regions of extended electron delocalization.
45.
Localization studies by GFP-labeled cell divisions proteins demonstrated that ADEP causes delocalization of Ftsz and inhibition of Z-Ring assembly in both species.
46.
The aim of the American Desk is to fold layers of inefficient bureaucracy, and prevent the delocalization of US corporate entities who employ US citizens.
47.
The reason that these complexes are so remarkably stable is due to significant delocalization of the cationic charge onto the Co 2 ( CO ) 6 moiety.
48.
The delocalization of the carbocation reduces the bond order of the polyene chain, thereby reducing the activation energy of the trans-to-cis isomerization.
49.
A well-studied example of delocalization that does not involve ? electrons ( hyperconjugation ) can be observed in the non-classical 2-Norbornyl cation.
50.
This stabilization is referred to as ?-aromaticity, cf . the cyclic delocalization of the six ? electrons in benzene as the archetypical example of aromaticity.
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