For many systems of physical and chemical kinetics, detailed balance provides " sufficient conditions " for the strict increase of entropy in isolated systems.
42.
Five years before Boltzmann, James Clerk Maxwell used the principle of detailed balance for gas kinetics with the reference to the principle of sufficient reason.
43.
In 1981, Carlo Cercignani and Maria Lampis proved that the Lorentz arguments were wrong and the principle of detailed balance is valid for polyatomic molecules.
44.
If different macroscopic processes are sampled from the same elementary microscopic events then macroscopic detailed balance may be violated even when microscopic detailed balance holds.
45.
This is valid for every bond configuration the system can pass through during its evolution, so detailed balance is satisfied for the total transition probability.
46.
If different macroscopic processes are sampled from the same elementary microscopic events then macroscopic detailed balance may be violated even when microscopic detailed balance holds.
47.
Values of the detailed balance limit are available in tabulated form and a MATLAB program for implementing the detailed balance model can be found at
48.
Values of the detailed balance limit are available in tabulated form and a MATLAB program for implementing the detailed balance model can be found at
49.
This means that black holes would not only absorb photons, but they would also have to emit them in the right amount to maintain detailed balance.
50.
For the equations of the law of mass action the reciprocal relations appear in the linear approximation near equilibrium as a consequence of the detailed balance conditions.
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