If the product and reactant concentrations are at equilibrium then the mass action ratio will equal the equilibrium constant.
42.
The Gibbs free energy is allowed to be negative and the equilibrium constant is allowed to go to infinity.
43.
Which relates the Gibbs energy to a chemical equilibrium constant, the van't Hoff equation can be derived.
44.
When this is done the equilibrium constant is obtained correctly from the rate equations for forward and backward reaction rates.
45.
The logarithmic form of the equilibrium constant equation is p " K " w = pH + pOH.
46.
An example of an experiment in which spectrophotometry is used is the determination of the equilibrium constant of a solution.
47.
This excluded volume effect increases the effective concentration of macromolecules ( increasing their rates and equilibrium constants of their reactions.
48.
This reaction yields an adsorbed complex A _ { ad } with an associated equilibrium constant K _ { eq}
49.
This definition is much more practical, but an equilibrium constant defined in terms of concentrations is dependent on conditions.
50.
A change in the concentrations of the reactants does not affect the equilibrium constant, but does affect the equilibrium position.
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