Ferrocene and its derivatives are antiknock agents added to the petrol used in motor vehicles, and are safer than the now-banned tetraethyllead.
42.
In terms of bonding, the iron center in ferrocene is usually assigned to the + 2 oxidation state, consistent with measurements using M�ssbauer spectroscopy.
43.
The crystal structure of octaphenylrhodocene shows a staggered conformation ( similar to that of ferrocene, and in contrast to the eclipsed conformation of ruthenocene ).
44.
Ferrocene can itself be oxidized to the ferrocenium cation ( Fc + ); the ferrocene / ferrocenium couple is often used as a reference in electrochemistry.
45.
Ferrocene can itself be oxidized to the ferrocenium cation ( Fc + ); the ferrocene / ferrocenium couple is often used as a reference in electrochemistry.
46.
The structure of ferrocene was confirmed by Wilkinson of Imperial College London shared a Nobel Prize for their work on metallocenes and other aspects of organometallic chemistry.
47.
The structure helped explain puzzles about ferrocene's conformers, the molecule features an iron atom " sandwiched " between two parallel cyclopentadienyl rings.
48.
Ferrocenium salts are sometimes used as one-electron oxidizing agents, and the reduced product, ferrocene, is inert and readily separated from ionic products.
49.
A further challenge arose with the discovery of ferrocene, the iron analogue of rhodocene and the first of the class of compounds now known as metallocenes.
50.
These centers bind to three adjacent sites of a metal such that the simple adducts have C 3v spin-crossover complex whereas ferrocene is low-spin.
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