It has been proposed that in the CK?-2 mechanism, ATP binds first, followed by choline, and then the transfer of the phosphoryl group takes place.
42.
The ends of DNA fragments are joined together by the formation of phosphodiester bonds between the 3'- hydroxyl of one DNA terminus with the 5'- phosphoryl of another.
43.
A bivalent metal ion, usually magnesium or cadmium, is required for enzymatic activity and has been shown to complex directly with the phosphoryl group esterified to the active-site serine.
44.
Tyr526, His506, Arg518 side chains and the oxygen from the backbone carbonyl group of Ala476 take part in the hydrogen bond network and assist in aligning the substrate for phosphoryl transfer.
45.
The enzyme-catalysed transfer of a phosphoryl group from allosterically inhibited by ATP and allosterically activated by AMP, thus indicating the cell's energetic needs when it undergoes the glycolytic pathway.
46.
This enzyme mechanism is an example of catalysis by approximation : the nucleoside-phosphate kinase binds the substrates to bring them together in the correct position for the phosphoryl group to be transferred.
47.
The second class of enzymes includes those where the Mg 2 + is complexed to nucleotide di-and tri-phosphates ( ADP and ATP ), and the chemical change involves phosphoryl transfer.
48.
Similarly, " open " conformation is generally referred to as the catalytically inactive form since Glu53 is not in close proximity to nucleoside 5'hydroxyl group and will not catalyze the phosphoryl transfer.
49.
For his discoveries in the field of bacterial chemotaxis, including the elucidation of flagellar phase variation and of flagellar motor activation by receptor-mediated signals transmitted through protein-phosphoryl-group transfers.
50.
Smithboro and its immediate area was evacuated on December 27, 1981 for a day after a train derailment, affecting 200 people . 22 of 84 trail cars derailed; dichlorodifluromethane and phosphoryl chloride were leaked.
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