1. This shows that the vibrational relaxation effectively depopulates the highest vibrational levels. 2. Additional Lindblad operators can be included to model various forms of dephasing and vibrational relaxation . 3. Only after vibrational relaxation , will there will be a realignment of their dipole moments. 4. The vibrational relaxation can be written as: 5. The T shape undergoes intramolecular vibrational relaxation , whereas the linear one directly breaks apart. 6. The Stokes shift is the result of two actions : Vibrational relaxation or dissipation and solvent reorganisation. 7. The vibrational relaxation of states B and C play an important role in the chemical kinetics of XeCl lasers. 8. The chemical kinetics due to collisional coupling of states B and C and vibrational relaxation are not well known. 9. If a C-H bond is over excited with too much vibration, the intramolecular vibrational relaxation takes 490 picoseconds. 10. A strong pressure induces a vibrational relaxation such that the values of v involved in the transfer are weak and vice versa for weak pressures.