asymmetric synthesis sentence in Hindi
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- The contributions of Rama Rao are reported to be noteworthy in the area of organic synthesis, especially asymmetric synthesis.
- Chiral sulfinimines as intermediates for the asymmetric synthesis of amines have also been developed by Franklin A . Davis.
- Tius has additionally developed a camphor-based auxiliary for achiral allenes that was employed in the first asymmetric synthesis of roseophilin.
- Aggarwal's work on asymmetric synthesis made it possible to selectively synthesise more of the form important to understanding biological processes.
- Both enantiomeric forms are commercially available and are relevant to the asymmetric synthesis of amines as a chiral ammonia equivalent.
- The second strategy is asymmetric synthesis : the use of various techniques to prepare the desired compound in high enantiomeric excess.
- Zinc has found many applications as catalyst in organic synthesis including asymmetric synthesis, being cheap and easily available alternative to precious metal complexes.
- "' 1, 1'- Bi-2-naphthol "'( BINOL ) is an organic compound that is often used as a ligand for transition-metal catalysed asymmetric synthesis.
- There is now an asymmetric synthesis available to prepare both dextromethadone [ S-( + )-methadone ] and levomethadone [ R-( " )-methadone ].
- There is now an asymmetric synthesis available to prepare both levomethadone [ R-( " )-methadone ] and dextromethadone [ S-( + )-methadone ].
- In "'biocatalysed asymmetric synthesis "', a non-chiral unit becomes chiral in such a way that the different possible stereoisomers are formed in different quantities.
- One example is the asymmetric synthesis of the drug warfarin ( in equilibrium with the hemiketal ) in a Michael addition of 4-hydroxycoumarin and benzylideneacetone:
- The most widely used method for the asymmetric synthesis of " N "-sulfinyl imines is the condensation of enantiopure primary sulfinamides with aldehyde or ketones.
- It is still possible to distinguish between the two enantiomers by using them control the asymmetric synthesis of another chemical whose stereochemical nature can be measured.
- For his discovery of chemical reactions-- the Sharpless Asymmetric Epoxidation, Dihydroxylation, and Aminohydroxylation-- which have revolutionized organic chemistry by transforming asymmetric synthesis from near-impossible to routine.
- Zeolites still cannot be obtained in enantiopure form, which precludes their applications in catalytic asymmetric synthesis, e . g ., for the pharmaceutical, agrochemical, and fragrance industries.
- The asymmetric synthesis of the Wieland-Miescher ketone ( 1985 ) is another intramolecular reaction also based on proline, that was explored by the Barbas group in 2000.
- In another example of asymmetric synthesis the ?, ?-unsaturated carbonyl compound first reacts with a syn : anti ratio of 8 : 1 and 97 % enantiomeric excess.
- The asymmetric synthesis of ( " S " )-( + )-2-methyltetrahydrofuran can achieved by using a wool rhodium complex as a chiral catalyst for hydrogenation of methyl furan.
- One application of a ring-opening reaction in asymmetric synthesis is that of trimethylsilylazide with an asymmetric ligand in " scheme 2 " in an organic synthesis of oseltamivir:
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