nucleophilic addition sentence in Hindi
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- Reformatsky enolates are less reactive than lithium enolates or Grignard reagents and hence nucleophilic addition to the ester group does not occur.
- Because the dimethylamide anion is a poor leaving group, the intermediate does not collapse and another nucleophilic addition does not occur.
- The term is also applied to certain nucleophilic addition reactions, such as in the acid catalyzed hydrolysis of nitriles to amides.
- Nucleophilic addition does not occur if kCO * ( the effective force constant for the CO ligand ) is below a threshold value
- The Mannich reaction is an example of nucleophilic addition of an amine to a carbonyl group followed by dehydration to the Schiff base.
- X-ray diffraction confirms sp2 hybridization at boron and its nucleophilic addition reaction with benzaldehyde gives further proof of the proposed structure.
- This mechanism can be referred to as an instance of the ANRORC mechanism : nucleophilic addition ( A N ), ring closing.
- The reaction type is nucleophilic addition of sulfur to a metal carbene formed from the diazoalkane followed by a Stevens-like rearrangement.
- Organometallic compounds, such as organolithium reagents, Grignard reagents, or acetylides, undergo nucleophilic addition reactions, yielding a substituted alcohol group.
- The nucleophilic addition at ethyl acrylate as an ?, ?-unsaturated carbonyl compound is a frequent strategy in the synthesis of pharmaceutical intermediates.
- The actual rearrangement reaction takes place when the amine group attacks the thiocarbonyl in a nucleophilic addition temporarily forming an aziridine and the thioacetamide by tautomerization.
- A monosaccharide can switch from the cyclic form, through a nucleophilic addition reaction between the carbonyl group and one of the hydroxyls of the same molecule.
- This mechanism involves a trimolecular reaction between the isocyanide ( R NC ), the carboxylic acid, and the carbonyl in a sequence of nucleophilic additions.
- The first step in the catalytic cycle reaction is the nucleophilic addition reaction of the oxone with the ketone group on the catalyst ( intermediate 1 ).
- Cram's rule predicts the majordiastereomer resulting from the "'diastereoselective "'nucleophilic addition to a carbonyl group next to a chiral center.
- The nucleophilic addition and the protonation of peptide amide nitrogen is a very fast process that is believed to occur as a single step in the catalytic process.
- A number of functional compounds with a variety of applications are available by nucleophilic addition at the activated double bond of the vinyl sulfonic acid and its derivatives.
- Nucleophilic addition of aminonitrile to CO 2 leads to cyano-carbamic acid, which undergoes an intramolecular ring closing to 5-imino-oxazolidin-2-one.
- The nucleophilic addition of urea gives the intermediate "'4 "', which quickly dehydrates to give the desired product "'5 " '.
- A hydroxide anion attacks one of the ketone groups in "'1 "'in a nucleophilic addition to the hydroxyl anion "'2 " '.
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