steric effect sentence in Hindi
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- Basic bonding and steric effects are at times insufficient to explain many structures, properties, and reactivity.
- The different geometries along the rotation paths can be rationalized in terms of mesomeric and steric effects ."
- Then the first push-pull diarylaminyls were synthesized and shown to have stabilities depending both on electronic and steric effects.
- Due to steric effects, second-order Markov effects may also play a role in the growth of some polymer chains.
- The Simmons Smith reaction is generally subject to steric effects, and thus cyclopropanation usually takes place on the less hindered face.
- In Figure 3, 1 is favored over 2 due to the large steric effect in 2 from the two phenyl groups.
- However, the steric effect makes it more difficult for the molecule to achieve the rearrangement transition state and form AD +.
- 2, 6-Lutidine is weakly nucleophilic, due to the steric effects of the two methyl groups on the ring nitrogen.
- Similarly to the Hammett ? value, the magnitude of ? will reflect to what extent a reaction is influenced by steric effects:
- "' Steric effects "'arise from a fact that each atom within a molecule occupies a certain amount of space.
- Other important factors include solvent choice, solution pH, steric effects, temperature, and the pressure of hydrogen inside the hydrogenation vessel.
- The regioselectivity of allylation mediated by indium in water is dependent on the steric effects of the substituents on both the intermediate and carbonyl.
- Also, the reaction rate was affected considerably by steric effects of 2-substituents, with more bulky groups increasing the rate of reaction.
- Electrostatic interactions are generally too weak to be considered traditional bonds or are prevented from forming a traditional bond, possibly by a steric effect.
- Steric effects of the alkyl substituents on the carbonyl reactant have been shown to affect both the rates and yields of B�chner Curtius Schlotterbeck reaction.
- Chad Tolman developed his ligand cone angle theory that developed into the widely accepted electronic and steric effects of ligands on inorganic and organometallic complexes.
- Of course, other effects can play a role in this selectivity process, including electronic effects, steric effects, and thermodynamic versus kinetic reaction control.
- A special computational procedure was developed to separate electronic and steric effects of an arbitrary group in the molecule and to reveal their influence on structure and reactivity.
- The "'Taft equation "'is a resonance effects influence reaction rates, the Taft equation also describes the steric effects of a substituent.
- Oftentimes, as with highly substituted dienes or very bulky dienophiles, steric effects can greatly influence " endo " / " exo " selectivity.
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