Oxidation tends to start at tertiary carbon atoms because free radicals here are more stable, so last longer and are attacked by oxygen.
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Oxidation tends to start at tertiary carbon atoms because the free radicals formed here are more stable and longer lasting, making them more susceptible to attack by oxygen.
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Also, if the chloride ion is not attached to a tertiary carbon atom or secondary carbon atom, then the carbocation formed ( R + ) will undergo a carbocation rearrangement reaction.
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