benzyne sentence in Hindi
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- Hence, benzyne possesses electrophilic character and undergoes reactions with nucleophiles.
- This result necessitated a symmetrical intermediate now known as benzyne.
- Anthranilic acid can be used in organic synthesis to generate benzyne.
- A detailed MO analysis of benzyne was presented in 1968.
- Alkyne and benzyne derivatives of titanocene are well known.
- Milder methods for benzyne generation have been developed.
- Extremely high temperatures are required for benzyne interconversion.
- HDDA generates benzyne, which can then be trapped, leading to diverse benzenoid products.
- The benzyne rapidly dimerizes to form biphenylene.
- This extensible trimerisation can generally include benzyne.
- Upon heating a solution of this complex, methane was lost, leaving the benzyne complex:
- It is a member of the unsaturated polycyclic hydrocarbons class of compounds and a tetramer of benzyne.
- The o-benzyne intermediate can be visualized in the two resonance ( chemistry ) forms illustrated above.
- Fluoride displacement of the trimethylsilyl group, as shown below, allows for generation of benzyne under mild conditions.
- Many radiomimetic compounds are enediynes, which undergo the Bergman cyclization reaction to produce the para-benzyne diradical.
- The p-benzyne diradical is highly reactive, and will abstract hydrogens from any possible hydrogen-donor.
- In 1953 John D . Roberts performed the classic 14 C labeling experiment, which provided strong support for benzyne.
- The discovery of benzyne led to rapid developments in synthetic methodologies to make this highly reactive intermediate useful for organic synthesis.
- Soon after Roberts discovery, Wittig and Pohmer found that benzyne can participate in [ 4 + 2 ] cycloaddition reactions.
- The free radical then continues on to cleave DNA in a similar manner to p-benzyne in order to treat cancerous cells.
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