dioxolane sentence in Hindi
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- The preparation of the isomeric compound sporol involved a similar dioxolane formation.
- The co-monomer is typically dioxolane but ethylene oxide can also be used.
- Dioxolane is formed by reaction of ethylene glycol with aqueous formaldehyde over an acid catalyst.
- TADDOLs consist of a dioxolane ring substituted with two mutually transoid diarylhydroxymethyl ( Ar 2 COH ) groups.
- Trioxane and Dioxolane are polymerized using an acid catalyst, often boron trifluoride etherate, BF 3 OEt 2.
- The dioxolane is expanded to the 1, 3-dioxane system found in sporol at a later step in the synthesis.
- The use of the urea complex, which gave a water-free material, successfully gave the dioxolane as the major product.
- "' Dioxolane "'is a peroxide . 1, 3-Dioxolane is used as a solvent and as a comonomer in polyacetals.
- "' Dioxolane "'is a peroxide . 1, 3-Dioxolane is used as a solvent and as a comonomer in polyacetals.
- By replacing the 1, 3-dioxolane group with an appropriate ring structure, various other types of putians have been synthesized, e . g.
- In the case of an allyl alcohol compound with a proximate carbonyl functional group, the epoxide can undergo a ring-expansion reaction to form a dioxolane.
- Substituting formaldehyde by other aldehydes or ketones results in a 2-substituted 1, 3-dioxolane ( yield : 70 85 %, catalyst : tetraethylammonium bromide ).
- In this case, the use of trifluoroperacetic acid derived from hydrogen peroxide, which therefore presumably contained traces of water, gave mostly a hemiacetal rather than the closed-ring dioxolane.
- This is because if TNP-ATP is acidified under mild conditions, it results in the opening of the dioxolane ring attached to the 2-oxygen, leaving a 3 O-TNP derivative as the only product.
- It is also an heterocyclic compound with a five-membered ring, and can be seen as a derivative of dioxolane, specifically "'4-ethyl-1, 3-dioxolan-2-one " '.
- In the case of neosporol, a Prilezhaev reaction with trifluoroperacetic acid is used to convert a suitable allyl alcohol precursor to an epoxide, which then undergoes a ring-expansion reaction with a proximate carbonyl functional group to form the dioxolane ring.
- TADDOLs ( tetraaryl-1, 3-dioxolane-4, 5-dimethanols ), which are derived from chiral tartaric acid, are a class of diol ligands often used to bind titanium, but have been adopted for zinc addition chemistry.
- The selectivity and speed of dimerization can be increased by adding a catalyst, such as platinum, platinum-palladium or iodine with sulfolan; however, 2-methyl-1, 3-dioxolane is formed as a side product in the last case.
- It is also an heterocyclic compound with a five-membered ring containing two oxygen atoms, and can be viewed as a derivative of dioxolane, namely " "'cis "-4, 5-dimethyl-1, 3-dioxolan-2-one " '.
- Lipid nanoparticles ( LNPs ) are being considered for delivering siRNA to silence AR . The most effective LNP to be found in vivo contains an ionizable cationic lipid 2, 2-dilinoleyl-4-( 2-dimethylaminoethyl )-[ 1, 3 ]-dioxolane ( DLin-KC2-DMA ).
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